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Mel doesn't make a move on Jayce in this AU because she assumes they're dating for real, like most people would. You'd think this would be out of character for her because she's good at reading people, so you'd think she'd be able to tell it was a sham. But no. The thing is, she's right: they are dating! They just don't know it yet.
Arcane AU where everything is mostly the same but at some point after the academy and before the events of the show Jayvik got married for the tax benefits and so Viktor could have a last name for practical reasons and basically it's a fake dating AU until someone else points out that neither of them seem even remotely bothered that this will impact their future romantic prospects with anyone outside their marriage